袍 usually appears in compounds: 旗袍 (qípáo, cheongsam), 长袍 (chángpáo, long robe), 袍子 (páozi, robe). On its own it sounds literary.
culture
The 旗袍 (qípáo) is one of the most iconic Chinese garments. Originally a Manchu garment, it evolved into the elegant form-fitting dress known worldwide.
Clothing radical on the left — the side-form of 衣. It files 袍 in the garment family with 衫 shirt, 裤 trousers, 袖 sleeve. A 袍 is a long robe — full-length clothing — so the radical does the obvious semantic work, naming the category outright.
Right side 包 supplies the páo sound (shifted from bāo) and a strong semantic echo. A robe wraps the body the way 包 'wraps' something inside — the whole graph reads as 'clothing that envelops', exactly what a flowing long garment does. Same root: 抱 embrace, 饱 full.