The everyday compound is the four-character idiom
龇牙咧嘴 — literally 'bare-teeth, twist-mouth', used for any pained or threatening grimace. It can describe (1) animals threatening to bite, (2) people contorted in pain or rage, or (3) ugly / fierce facial expressions. The single verb
龇 standalone, as in
龇着牙 (with teeth bared), is colloquial and vivid — common in novels and casual writing.