立陶宛 (Lìtáowǎn) is the standard transliteration of Lithuania, and the suffix
人 ('person') turns any country name into its nationality:
中国人 Chinese,
美国人 American,
立陶宛人 Lithuanian. The Xinhua entry notes Lithuanians (~3.34M as of 1985) are the dominant ethnic group of Lithuania, mostly Catholic, with diaspora communities in the US, Canada, and Poland.