雌黄 is an actual yellow mineral, arsenic trisulfide (As2S3). Ancient Chinese scribes used it as an early correction fluid: dabbed onto bamboo or yellow paper, it covered miswritten characters. From this came the famous idiom
信口雌黄 - literally "orpiment from the mouth" - meaning "to spout corrections irresponsibly," hence "to talk nonsense / slander baselessly."