炮 has a second reading
炮 for traditional medicine preparation — to roast or parch herbs in a pan. It survives in
炮制 (to prepare herbs by roasting; now also figuratively "to concoct, fabricate") and the historical torture
炮烙 (burning-pillar). Dictionaries also list a rare
炮 for quick-fry cooking, but in modern usage you'll almost never see it. Default to pào, switch to páo only for
炮制 and
炮烙.