捉 is often used for catching animals or in set phrases. 捉迷藏 (zhuō mí cáng) = hide and seek. 捉弄 (zhuō nòng) = to tease/play tricks on someone. For catching criminals, 抓 (zhuā) is more common in modern speech.
culture
捉摸不定 (zhuō mō bù dìng) = unpredictable, hard to figure out. 捉襟见肘 (zhuō jīn jiàn zhǒu) = to be in financial straits (pulling your lapel exposes your elbow — clothes too small).